But many molecular biological processes can induce torsional strain.
2.
Angle strain and torsional strain combine to create ring strain that affects cyclic molecules.
3.
They occur at the flanks of transcribed regions, in 5?introns, and also at gene torsional strain.
4.
In mononuclear complexes with large m and n, the rings will rotate to reduce torsional strain within the linker arms.
5.
Torsional strain occurs when atoms separated by three bonds are placed in an eclipsed conformation instead of the more stable staggered conformation.
6.
This transannular strain, also known as Prelog strain, occurs when the cyclic molecules attempt to avoid angle and torsional strain.
7.
In this case torsional strain between the bulky tert-butyl group and the adjacent methylenes is relieved upon oxidation at C3.
8.
When the ring oxygen is not in the plane the substituents eclipse and when it is in the plane torsional strain is relieved.
9.
The B form of the DNA helix twists 360?per 10.4-10.5 bp in the absence of torsional strain.
10.
It was found that a combination of angle strain, torsional strain, and Pauli repulsion leads to the extreme destabilization experienced in this molecule.
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